Synthetic polymer fibres

Introduction

Synthetic polymer fibres can be classified based on the general chemical mechanism used for building the linear polymers.

Synthetic fibres: Condensation polymers - polyamide (Nylon) polyester;  Addition polymers - polyvinilalcohol, polyolefin, polyacrylic;  Block copolymers - elastane
Fibre type Fibre composition Cross-section appearance
Polyester Poly(ethylene-terephthalate) Depends on spinneret
Nylon polyamide Depends on spinneret
Acrylic Poly-acrylonitrile Depends on spinning conditions
Polypropylene polypropylene Depends on spinneret
Elastane polyurethane fibrillar
Synthetic polymer fibres

Click on the headings below for more information



Polyester-PES


  • Variants – PET most common
  • Methylene groups, Carboxyl groups, ester link, benzen rings
  • DP 115-140
  • 65% Crystalline 35% amorphous
  • Highly oriented in amorphous areas
  • Very useful – most used synthetic fibre
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Polyamide-PA


  • First synthetic fibre 1939, DuPont
  • Parachutes, shirts, underwear, carpets, outdoor clothing
  • Today substituted by PES/Cotton in shirts, underwear etc.
      Nylon
    • Amide groups
    • Degree of polymerisation (DP): 50-80
    • Zig-zag molecule chain, high crystalline and orientation
    • 65-85% crystalline 15-35% amorphous
    • Nylon 6 (PA6) and Nylon 6.6 (PA6.6)
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Acrylic-PAN


  • 1950 DuPont
  • Homo-polymer – Compact structure – Bikryl®
  • Co-Polymer open structure – Acrilan®
  • DP ~ 1000
  • Wet or Dry spinning, no melt spinning
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Polypropylene-PP


  • Methyl groups
  • Crystalline 50-65%
  • Cheap process
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Elastane-EL


  • 1959 – DuPont
  • Elastomeric fibre
  • Hard and soft segments
  • Stretched repeatedly return to original length
  • Blended with other fibres
  • Spandex® Lycra®
closeup of lycra fibre
closeup of a elastic yarn
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Questions

Pair the following international fibre abbreviations with the correct generic fibre name:

PAN ?

  1.   Polyester  
  2.   Acrylic  
  3.   Polyamide  
  4.   Lyocell  

PES ?

  1.   Polyester  
  2.   Acrylic  
  3.   Polyamide  
  4.   Lyocell  

PA ?

  1.   Polyester  
  2.   Acrylic  
  3.   Polyamide  
  4.   Lyocell  

CLY ?

  1.   Polyester  
  2.   Acrylic  
  3.   Polyamide  
  4.   Lyocell  

The shape and size (cross section) of manufactured fibres are determined by:

  1.   It's elongation properties.  
  2.   The holes in the spinnerets.  
  3.   The amount of crimp in the fibre.  
  4.   It's origin.  

A triangular shaped fibre will feel harsher and hide soil better than a round fibre.

  1.   True  
  2.   False  

What changes in the spinneret would have to be done for the following to occur:

Thicker filament fibres?

  1.   Larger holes  
  2.   Smaller holes  
  3.   More holes  
  4.   Less holes  
  5.   Change shape of holes  

Produce more fibres?

  1.   Larger holes  
  2.   Smaller holes  
  3.   More holes  
  4.   Less holes  
  5.   Change shape of holes  

Change cross-section shape ?

  1.   Larger holes  
  2.   Smaller holes  
  3.   More holes  
  4.   Less holes  
  5.   Change shape of holes  
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This resource was developed as part of an Erasmus+ project, funded with support from the European Commission under grant agreement 2016-1-SE01-KA203-22064.

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