Dye classification

Dyes can be categorised according to several factors such as colour, synthetic route, fibre type, the method of application to the substrate and chemical structure, etc.

Classification of dye by method of application (click each for more information):

  1. Which two fibres can be dyed with both reactive dyes and acid dyes?
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  3. Which dye class is used for dyeing acrylic fibre? What kind of bond is created during this dyeing?
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  5. Which fibre can be dyed with basic dyes?
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  7. Which dye class do you use to dye a polyester knitted sweater with 5% elastane elastomer?
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  9. Name 2 dye classes that can be used for dying polyamide.
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Direct dyes


Substrate

Mainly used for cellulosic fibres: cotton, viscose, linen. Can also be applied on silk and wool.

Method

Applied directly to the substrate in a neutral or alkaline bath.

Fastness

Give bright shades but exhibit poor wash and light-fastness. After-treatments with dye fixing agent.

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Reactive dyes


Substrate

Commonly used for all cellulosic fibres: wool, silk and rayon.

Method

Reacts chemically with the fibre being dyed.

Fastness

Very good fastness properties.

×

Vat dyes


Substrate

Cotton, linen, rayon, wool, silk and sometimes nylon.

Method

Insoluble in water. Requires reduction treatment to make soluble in water and oxidation to resume insoluble state after dyeing.

Fastness

High fastness to chlorine, washing, light, rubbing and boiling.

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Sulphur dyes


Substrate

Cotton, linen and rayon.

Method

Insoluble in water, similar to vat dyes.

Fastness

Excellent resistance to washing but poor resistance to sunlight.

×

Azoic dyes


Substrate

Cotton, linen and viscose.

Method

Insoluble in water. Two components react to produce the dye (Coupling Compound (Naphthol) and Di‐azo –compound).

Fastness

Good fastness properties.

×

Metal complex dyes


Substrate

Wool, nylon and silk.

Method

Pre-metallised dyes, pH<7.

Fastness

Good fastness properties due to high molecular size and metal complex structure.

×

Acid dyes


Substrate

Wool, nylon and silk.

Method

Applied from a dye bath containing acids.

Fastness

Fastness properties may vary among individual dyes and fibre types.

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Disperse dyes


Substrate

Nylon, polyester and cellulose acetate.

Method

Insoluble in water, pH 4-5. Diffuse into the fibre at high temperatures.

Fastness

Good fastness properties.

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Basic dyes


Substrate

Mainly used for Acrylic.

Method

Generally pH<7. Reaction with acidic groups.

Fastness

Good fastness properties.

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